1,4-Addition of silicon dienoates to α,β-unsaturated aldehydes catalyzed by in situ-generated silicon Lewis acid.
نویسندگان
چکیده
In situ-generated silyl methide species (R(3)Si-CTf(2)R') effectively catalyzed the reaction of β-substituted α,β-unsaturated aldehydes with silicon dienoates such as 3-bromo-2-TESO-furan to give the corresponding γ-adducts with excellent 1,4-selectivity and good anti selectivity.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 46 شماره
صفحات -
تاریخ انتشار 2010